Experiments probing correlations between spin-1/2 nuclei (I) and nuclear spins (S) with large anisotropic interactions (quadrupolar or chemical shift anisotropy ) often offer valuable access routes to molecular structures and dynamics. In such experiments, development of efficient correlation schemes is not trivial and constitutes an ever-evolving theme of research. As these experiments are performed routinely under MAS, interference between the RF filed and the large time- dependent quadrupolar or chemical shift anisotropic interaction leads to complex spin dynamics, often leading to poor and orientation-dependent transfer efficiency.
Supervisor
Dr. Jayanthi S
Department